They’ve collaborated on a film (“Mr. and Mrs. Smith”) and a flurry of kiddos, and now Brad Pitt and Angelina Jolie are joining forces for a new wine business.

The “Fight Club” hunk and his “Sky Captain and the World of Tomorrow” lady plan to sell the fruit of the vine from their French estate Chateau Miraval.

Brad told press, “We are intimately involved and quite enthused over the wine project with our friends the Perrin family.”

Miraval is a rosé that was previously sold under the Pink Floyd moniker. Partner Marc Perrin explained, “Brad and Angelina are very friendly, nice people and down to earth. They’re thinking long term. If you knew Brad and Angelina, you would see they are in search of perfection in everything.”